OLED-Organic Light Emitting Diode





OLED:

          An OLED (organic light-emitting diode) is a light-emitting diode (LED) in which the emissive electroluminescent layer is a film of organic compound which emits light in response to an electric current. This layer of organic semiconductor is situated between two electrodes. Generally, at least one of these electrodes is transparent. OLEDs are used to create digital displays in devices such as television screens, computer monitors, portable systems such as mobile phoneshandheld games consoles and PDAs. A major area of research is the development of white OLED devices for use in solid-state lightingapplications.







History:

          The first observations of electroluminescence in organic materials were in the early 1950s by André Bernanose and co-workers at theNancy-Université, France. They applied high-voltage alternating current (AC) fields in air to materials such as acridine orange, either deposited on or dissolved in cellulose or cellophane thin films. The proposed mechanism was either direct excitation of the dye molecules or excitation of electrons.
In 1960, Martin Pope and co-workers at New York University developed ohmic dark-injecting electrode contacts to organic crystals.[8][9][10] They further described the necessary energetic requirements (work functions) for hole and electron injecting electrode contacts. These contacts are the basis of charge injection in all modern OLED devices. Pope's group also first observed direct current (DC) electroluminescence under vacuum on a pure single crystal of anthracene and on anthracene crystals doped with tetracene in 1963 using a small area silver electrode at 400 V. The proposed mechanism was field-accelerated electron excitation of molecular fluorescence.
Pope's group reported in 1965 that in the absence of an external electric field, the electroluminescence in anthracene crystals is caused by the recombination of a thermalized electron and hole, and that the conducting level of anthracene is higher in energy than the exciton energy level. Also in 1965, W. Helfrich and W. G. Schneider of the National Research Council in Canada produced double injection recombination electroluminescence for the first time in an anthracene single crystal using hole and electron injecting electrodes. the forerunner of modern double injection devices. In the same year, Dow Chemical researchers patented a method of preparing electroluminescent cells using high voltage (500–1500 V) AC-driven (100–3000 Hz) electrically insulated one millimetre thin layers of a melted phosphor consisting of ground anthracene powder, tetracene, and graphite powder. Their proposed mechanism involved electronic excitation at the contacts between the graphite particles and the anthracene molecules.
Electroluminescence from polymer films was first observed by Roger Partridge at the National Physical Laboratory in the United Kingdom. The device consisted of a film of poly(n-vinylcarbazole) up to 2.2 micrometres thick located between two charge injecting electrodes. The results of the project were patented in 1975 and published in 1983.
The first diode device was reported at Eastman Kodak by Ching W. Tang and Steven Van Slyke in 1987. This device used a novel two-layer structure with separate hole transporting and electron transporting layers such that recombination and light emission occurred in the middle of the organic layer. This resulted in a reduction in operating voltage and improvements in efficiency and led to the current era of OLED research and device production.
Research into polymer electroluminescence culminated in 1990 with J. H. Burroughes et al. at the Cavendish Laboratory in Cambridge reporting a high efficiency green light-emitting polymer based device using 100 nm thick films of poly(p-phenylene vinylene).




Working principle:

                                  A typical OLED is composed of a layer of organic materials situated between two electrodes, the anode and cathode, all deposited on a substrate. The organic molecules are electrically conductive as a result of delocalization of pi electrons caused by conjugation over all or part of the molecule. These materials have conductivity levels ranging from insulators to conductors, and therefore are consideredorganic semiconductors. The highest occupied and lowest unoccupied molecular orbitals (HOMO and LUMO) of organic semiconductors are analogous to the valence and conductionbands of inorganic semiconductors.
Originally, the most basic polymer OLEDs consisted of a single organic layer. One example was the first light-emitting device synthesised by J. H. Burroughes et al., which involved a single layer of poly(p-phenylene vinylene). However multilayer OLEDs can be fabricated with two or more layers in order to improve device efficiency. As well as conductive properties, different materials may be chosen to aid charge injection at electrodes by providing a more gradual electronic profile,or block a charge from reaching the opposite electrode and being wasted. Many modern OLEDs incorporate a simple bilayer structure, consisting of a conductive layer and an emissive layer. More recent developments in OLED architecture improves quantum efficiency (up to 19%) by using a graded heterojunction. In the graded heterojunction architecture, the composition of hole and electron-transport materials varies continuously within the emissive layer with a dopant emitter. The graded heterojunction architecture combines the benefits of both conventional architectures by improving charge injection while simultaneously balancing charge transport within the emissive region.
During operation, a voltage is applied across the OLED such that the anode is positive with respect to the cathode. Anodes are picked based upon the quality of their optical transparency, electrical conductivity, and chemical stability. A current of electrons flows through the device from cathode to anode, as electrons are injected into the LUMO of the organic layer at the cathode and withdrawn from the HOMO at the anode. This latter process may also be described as the injection of electron holes into the HOMO. Electrostatic forces bring the electrons and the holes towards each other and they recombine forming an exciton, a bound state of the electron and hole. This happens closer to the emissive layer, because in organic semiconductors holes are generally more mobile than electrons. The decay of this excited state results in a relaxation of the energy levels of the electron, accompanied by emission of radiation whosefrequency is in the visible region. The frequency of this radiation depends on the band gap of the material, in this case the difference in energy between the HOMO and LUMO.
As electrons and holes are fermions with half integer spin, an exciton may either be in a singlet state or a triplet state depending on how the spins of the electron and hole have been combined. Statistically three triplet excitons will be formed for each singlet exciton. Decay from triplet states (phosphorescence) is spin forbidden, increasing the timescale of the transition and limiting the internal efficiency of fluorescent devices. Phosphorescent organic light-emitting diodes make use of spin–orbit interactions to facilitate intersystem crossingbetween singlet and triplet states, thus obtaining emission from both singlet and triplet states and improving the internal efficiency.
Indium tin oxide (ITO) is commonly used as the anode material. It is transparent to visible light and has a high work function which promotes injection of holes into the HOMO level of the organic layer. A typical conductive layer may consist of PEDOT:PSS as the HOMO level of this material generally lies between the workfunction of ITO and the HOMO of other commonly used polymers, reducing the energy barriers for hole injection. Metals such as barium and calcium are often used for the cathode as they have low work functionswhich promote injection of electrons into the LUMO of the organic layer. Such metals are reactive, so they require a capping layer ofaluminium to avoid degradation.
Experimental research has proven that the properties of the anode, specifically the anode/hole transport layer (HTL) interface topography plays a major role in the efficiency, performance, and lifetime of organic light emitting diodes. Imperfections in the surface of the anode decrease anode-organic film interface adhesion, increase electrical resistance, and allow for more frequent formation of non-emissive dark spots in the OLED material adversely affecting lifetime. Mechanisms to decrease anode roughness for ITO/glass substrates include the use of thin films and self-assembled monolayers. Also, alternative substrates and anode materials are being considered to increase OLED performance and lifetime. Possible examples include single crystal sapphire substrates treated with gold (Au) film anodes yielding lower work functions, operating voltages, electrical resistance values, and increasing lifetime of OLEDs.
Single carrier devices are typically used to study the kinetics and charge transport mechanisms of an organic material and can be useful when trying to study energy transfer processes. As current through the device is composed of only one type of charge carrier, either electrons or holes, recombination does not occur and no light is emitted. For example, electron only devices can be obtained by replacing ITO with a lower work function metal which increases the energy barrier of hole injection. Similarly, hole only devices can be made by using a cathode made solely of aluminium, resulting in an energy barrier too large for efficient electron injection.



Advantages:

 Lower cost in the future



OLEDs can be printed onto any suitable substrate by an inkjet printer or even by screen printing, theoretically making them cheaper to produce than LCD or plasma displays. However, fabrication of the OLED substrate is more costly than that of a TFT LCD, until mass production methods lower cost through scalability. Roll-to-roll vapour-deposition methods for organic devices do allow mass production of thousands of devices per minute for minimal cost, although this technique also induces problems in that devices with multiple layers can be challenging to make because of registration, lining up the different printed layers to the required degree of accuracy.
Lightweight and flexible plastic substrates
OLED displays can be fabricated on flexible plastic substrates leading to the possible fabrication of flexible organic light-emitting diodes for other new applications, such as roll-up displays embedded in fabrics or clothing. As the substrate used can be flexiblesuch as polyethylene terephthalate (PET),the displays may be produced inexpensively.
Wider viewing angles and improved brightness
OLEDs can enable a greater artificial contrast ratio (both dynamic range and static, measured in purely dark conditions) and a wider viewing angle compared to LCDs because OLED pixels emit light directly. OLED pixel colors appear correct and unshifted, even as the viewing angle approaches 90° from normal.
Better power efficiency and thickness
LCDs filter the light emitted from a backlight, allowing a small fraction of light through. So, they cannot show true black. However, an inactive OLED element does not produce light or consume power, thus allowing true blacks.Dismissing the backlight also makes OLEDs lighter because some substrates are not needed. This allows electronics potentially to be manufactured more cheaply, but, first, a larger production scale is needed, because OLEDs still somewhat are niche products. When looking at top-emitting OLEDs, thickness also plays a role when talking about index match layers (IMLs). Emission intensity is enhanced when the IML thickness is 1.3–2.5 nm. The refractive value and the matching of the optical IMLs property, including the device structure parameters, also enhance the emission intensity at these thicknesses.
Response time
OLEDs also can have a faster response time than standard LCD screens. Whereas LCD displays are capable of between 1 and 16 ms response time offering a refresh rate of 60 to 480 Hz, an OLED theoretically can have a response time less than 0.01 ms, enabling a refresh rate up to 100,000 Hz .OLEDs also can be run as a flicker display, similar to a CRT, in order to eliminate the sample-and-hold effect that creates motion blur on OLEDs.

Disadvantages:

Current costs
OLED manufacture currently requires process steps that make it extremely expensive. Specifically, it requires the use of low-temperature polysilicon backplanes; LTPS backplanes, in turn, require laser annealing from an amorphous silicon start. This part of the manufacturing process for AMOLEDs starts with similar process costs to a standard LCD, and then adds a further process, lengthening the entire manufacturing step. Currently, large-area glass substrates are out of scale for AMOLED devices.
Lifespan
The biggest technical problem for OLEDs was the limited lifetime of the organic materials. One 2008 technical report on an OLED TV panel found that "After 1,000 hours the blue luminance degraded by 12%, the red by 7% and the green by 8%.In particular, blue OLEDs historically have had a lifetime of around 14,000 hours to half original brightness (five years at 8 hours a day) when used for flat-panel displays. This is lower than the typical lifetime of LCD, LED or PDP technology. Each currently is rated for about 25,000–40,000 hours to half brightness, depending on manufacturer and model. Degradation occurs because of the accumulation of nonradiative recombination centers and luminescence quenchers in the emissive zone. It is said that the chemical breakdown in the semiconductors occurs in four steps: 1) recombination of charge carriers through the absorption of UV light, 2) hemolytic dissociation, 3)subsequent radical addition reactions that form π radicals, and 4) disproportionation between two radicals resulting in hydrogen-atom transfer reactions. However, some manufacturers' displays aim to increase the lifespan of OLED displays, pushing their expected life past that of LCD displays by improving light outcoupling, thus achieving the same brightness at a lower drive current.In 2007, experimental OLEDs were created which can sustain 400 cd/m2 ofluminance for over 198,000 hours for green OLEDs and 62,000 hours for blue OLEDs.
Color balance issues
Additionally, as the OLED material used to produce blue light degrades significantly more rapidly than the materials that produce other colors, blue light output will decrease relative to the other colors of light. This variation in the differential color output will change the color balance of the display and is much more noticeable than a decrease in overall luminance. This can be avoided partially by adjusting color balance, but this may require advanced control circuits and interaction with the user, which is unacceptable for some users. More commonly, though, manufacturers optimize the size of the R, G and B subpixels to reduce the current density through the subpixel in order to equalize lifetime at full luminance. For example, a blue subpixel may be 100% larger than the green subpixel. The red subpixel may be 10% smaller than the green.
Efficiency of blue OLEDs
Improvements to the efficiency and lifetime of blue OLEDs is vital to the success of OLEDs as replacements for LCD technology. Considerable research has been invested in developing blue OLEDs with high external quantum efficiency as well as a deeper blue color. External quantum efficiency values of 20% and 19% have been reported for red (625 nm) and green (530 nm) diodes, respectively.However, blue diodes (430 nm) have only been able to achieve maximum external quantum efficiencies in the range of 4% to 6%.
Water damage
Water can damage the organic materials of the displays. Therefore, improved sealing processes are important for practical manufacturing. Water damage especially may limit the longevity of more flexible displays.
Outdoor performance
As an emissive display technology, OLEDs rely completely upon converting electricity to light, unlike most LCDs which are to some extent reflective. e-paper leads the way in efficiency with ~ 33% ambient light reflectivity, enabling the display to be used without any internal light source. The metallic cathode in an OLED acts as a mirror, with reflectance approaching 80%, leading to poor readability in bright ambient light such as outdoors. However, with the proper application of a circular polarizer and antireflective coatings, the diffuse reflectance can be reduced to less than 0.1%. With 10,000 fc incident illumination (typical test condition for simulating outdoor illumination), that yields an approximate photopic contrast of 5:1.
Power consumption
While an OLED will consume around 40% of the power of an LCD displaying an image that is primarily black, for the majority of images it will consume 60–80% of the power of an LCD. However, an OLED can use more than three times as much power to display an image with a white background, such as a document or web site.This can lead to reduced battery life in mobile devices, when white backgrounds are used.

Refer:http://en.wikipedia.org/wiki/OLED#cite_note-65

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